First Seria A hat-trick

On 22 March 2014, Immobile scored his first Serie A hat-trick, in a 3–1 win against Livorno. Three days later, he scored a spectacular volley with his left foot against Roma, temporarily bringing the Granata level at the Stadio Olimpico. On 6 April, he scored the winning goal against Catania in a 2–1 victory.